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Ceramicule

A ceramicule is a new type of inorganic complex of metal and oxygen atoms organized into stable nano-clusters as small as 3 nm.[1][2][3] As shown in the references, colloidal ceria is a proven example. In this case the complex are stabilized by organic molecules at the surface.


The term comes from ceramic and molecule, more commonly associated with organic compounds.



References

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  1. ^ Karmalkar, Deepika G.; Sankaralingam, Muniyandi; Seo, Mi Sook; Ezhov, Roman; Lee, Yong-Min; Pushkar, Yulia N.; Kim, Won-Suk; Fukuzumi, Shunichi; Nam, Wonwoo. "A High-Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity". Angewandte Chemie International Edition. 0 (0). doi:10.1002/anie.201910032. ISSN 1521-3773.
  2. ^ Mukhopadhyay, Sumitra; Mandal, Sanjay K.; Bhaduri, Sumit; Armstrong, William H. (2004-09-01). "Manganese Clusters with Relevance to Photosystem II". Chemical Reviews. 104 (9): 3981–4026. doi:10.1021/cr0206014. ISSN 0009-2665.
  3. ^ Mitchell, Kylie J.; Abboud, Khalil A.; Christou, George (2017-11-13). "Atomically-precise colloidal nanoparticles of cerium dioxide". Nature Communications. 8 (1): 1–7. doi:10.1038/s41467-017-01672-4. ISSN 2041-1723.
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